JEE Advanced Chemistry Syllabus 2022

·   Detection and Identification of the groups: Alcoholic, Phenolic, Aldehyde, Ketone, Amino, and Nitro chemical methods from binary mixtures

·   Amines: Basic of Substituted Anilines and Aliphatic amines, Nitro compounds, reaction with nitro acids, azo coupling reaction of diazonium salts, carbylamine reactions

·   Carboxylic Acids: Reactions of ester, acid chlorides and amides, ester hydrolysis

·   Haloform reaction and Grignard addition

·   Cannizaro reaction

·   Aldol condensation, Perkin reactions

·   Aldehydes and Ketones: Oxide reactions, reduction reactions, oxime, and hydrogen reactions

·   Ethers: Preparation by William’s synthesis

·   Alkyl Halides: rearrangement reactions of alkyl carbocation, nucleophilic substitution reactions, Grignard reactions

·   Alcohols: esterification, dehydration and oxidation, reaction with sodium, phosphorus halides, ZnCl2/ concentrated HCL, conversion of alcohols into aldehydes and ketones

·   Electrophilic substitution reactions like Friedel-Crafts Alkylation and Acylation

·   Halogenation

·   Nitration

·   Sulphonation

·   Structure of Benzene and automaticity

·   Physical properties of alkane like melting point, boiling point and density of alkanes and homologous series

·   Preparation of Alkanes by Wurtz reaction decarboxylation reactions

·   Cellulose

·   Nylon

·   Teflon

·   PVC

·   Classification of Carbohydrates

·   Reduction

·   Oxidation

·   Glycoside formation

·   Hydrolysis of sucrose

·   Kolbe Reactions

·   Electrophilic substitution reaction

·   Acidity

·   Preparation of alkynes and alkenes by elimination reactions

·   Electrophilic addition reactions of alkenes with X2, HOX, HX, and H2O (X= Halogen)

·   Addition reactions of alkynes

·   Metal acetylides

·   Reactions of alkenes with KMnO4 and Ozone

·   Physical properties of alkenes and alkynes

·   Acidity

·   Acid-catalyzed hydration of alkenes and alkynes

·   Shapes of Organic Molecules

·   Hybridisation of Carbon

·   Structural and geometrical isomerism

·   IUPAC nomenclature of simple organic compounds

·   Optical isomerism of compounds containing up to two asymmetric centers

·   Resonance and hyperconjugation

·   Newman projections

·   Keto-enol tautomerism

·   Inductive and resonance effects on acidity and basicity of organic acids and bases

·   Polarity and inductive effects in alkyl halides  

·   Formation, structure, and stability of carbocations, carbanions, and free radicals

·   Reactive intermediates produced during homolytic and heterolytic bond cleavage

·   Determination of empirical and molecular formulae of simple compounds Hydrogen Bonds

·   Nitrogen

·   Silicon

·   Phosphorus

·   Oxygen

·   Sulphur

·   Halogens

·   Properties of allotropes of carbon, phosphorus and sulphur

·   Hybridization and geometries of mononuclear coordination compounds

·   Definition

·   General characteristics

·   Oxidation states and their stabilities, color, calculation of spin-only magnetic moment

·   Nitrate

·   Halides (excluding Fluoride)

·   Sulphate

·   Sulphide

·   Hydroxides

·   Peroxides

·   Bicarbonates

·   Carbonates

·   Chlorides

·   Sulphates

·   Magnesium

·   Potassium

·   Calcium

·   Halogens: hydrohalic acids, bleaching powder, oxides and oxyacids of chlorine, Xenon fluorides

·   Oxygen: ozone and hydrogen peroxide

·   Sulphur: oxides, oxyacids and ammonia

·   Silicon: silicones, silicates and silicon carbide

·   Boron: diborane, boric acid and borax

·   Aluminium: alumina, aluminium chloride and alums

·   Oxides and chlorides of tin and lead

·   Potassium permanganate

·   Silver thiosulphate

·   Silver oxide

·   Silver nitrate

·   Potassium dichromate

·   Oxides, chlorides and sulphates of Fe2+, Zn2+ and Cu2+

·   Self reduction method

·   Cyanide process

·   Average

·   Root mean square

·   Most probable velocities and their relation with Temperature

·   Law of Partial Pressures

·   Law of Vapour Pressures

·   Van der waals equations

·   Diffusion of gases

·   Ideal gas equation

·   Concept of solid and liquid states

·   Deviation from Ideality  

·   Internal energy, work and heat calculations  

·   Reaction of heat, fusion and evaporation

·   Entropy

·   Free Energy

·   Second law of Thermodynamics

·   Specific, equivalent and molar conductivity

·   Kohlrausch’s law

·   Concentration cells

·   Faraday’s laws of electrolysis

·   Nernst equation and its relation to delta (G)

·   Electrochemical cells

·   Reactions of cells

·   Packing in fcc, bcc and hcp latticeslonic compounds

·   Point defects

·   Seven crystal systems

·   Classification of solid

·   Crystalline state

·   Elementary ideas of emulsions, surfactants and micelles

·   Elementary concepts of adsorption

·   Quantum numbers

·   Spectrum of the hydrogen atom

·   Electronic configurations of elements

·   Pauli’s exclusion principle and Hund’s rule

·   Hydrogen Bond

·   VSEPR model and shapes of molecules

·   Orbital energy diagrams for homonuclear diatomic species

·   Uncertainty principles  

·   PH and buffer solutions

·   Acids and bases

·   Hydrolysis of salts effect concentration, temperature and pressure

·   Rates of chemical reactions

·   First order reactions

·   Arrhenius equation

·   Molecular weight determination from lowering of vapor pressure

·   Characteristics of α, β, and γ rays fission and fusion reactions

·   Dalton’s theory

·   Chemical formulas

·   Chemical equations

·   Oxidation-reduction

·   Calculations

·   Displacement reactions

·   Mole Fractions

·   Molarity

·   Molality

·   Normality